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    • 专利摘要:
    The invention relates to the use of one or more soluble fatty amines in a lubricating composition for preventing and / or reducing the metallic losses of parts of an engine, preferably a marine engine. The invention also relates to a method for preventing and / or reducing the metallic losses of the parts of an engine, in particular a marine engine in which said parts are brought into contact with one or more soluble fatty amines in a lubricating composition.
    公开号:FR3039835A1
    申请号:FR1557492
    申请日:2015-08-03
    公开日:2017-02-10
    发明作者:Valerie Doyen；Celine Chalancon
    申请人:Total Marketing Services SA；
    IPC主号:
    专利说明:

    USE OF A FATTY AMINE FOR PREVENTING AND / OR REDUCING METALLIC LOSS OF PARTS IN AN ENGINE
    The present invention relates to the prevention and / or reduction of metallic losses of parts of an engine, in particular of a marine engine. More particularly, the present invention relates to the prevention and / or reduction of metallic losses of parts of a marine engine due to the contact of these parts with an acid medium.
    The subject of the present invention is the use of one or more soluble fatty amines in a lubricant composition for preventing and / or reducing the metallic losses of parts of an engine, in particular of a marine engine.
    The present invention also relates to a method for preventing and / or reducing the metallic losses of parts of an engine, in particular a marine engine in which said parts are brought into contact with one or more fatty amines soluble in a composition lubricating.
    The combustion of fuel oils generates acid gases, in particular sulfur oxides (SO2, SO3). These acid gases are, among other things, combustion residues of the fuel oils; these residues are in contact with the lubricating oil, and therefore are also in contact with the engine parts. In contact with the moisture present in the combustion gases and / or in the lubricating oil, these acid gases hydrolyze to sulphurous acid (HSO3) or sulfuric acid (H2SO4), which are in turn in contact with the parts of the engine.
    In the case of marine engines, especially two-stroke marine engines, lubricating oils are classified into two categories: cylinder oils, on the one hand, ensuring the lubrication of the cylinder piston assembly, and system oils on the other hand, ensuring the lubrication of all moving parts other than those of the cylinder piston assembly. More specifically, it is within the piston cylinder assembly that the combustion residues containing acid gases are in contact with the lubricating oil.
    In general, the neutralization of these acids is carried out by reaction with the basic sites included in the lubricant. The capacity of neutralization of an oil is measured by its BN or Base Number in English, characterizing its basicity. Π is measured according to standard ASTM D-2896 and is expressed in equivalent weight of potash per gram of oil or mg of KOH / g of oil. The BN is a standard criterion for adjusting the basicity of cylinder oils to the sulfur content of the fuel used, in order to neutralize all the sulfur contained in the fuel, and likely to be converted into sulfuric acid by combustion and hydrolysis.
    Specifically, marine oils available on the market have a BN ranging from 5 to 130 mg KOH / g oil. This basicity is in particular provided by detergents which are overbased by insoluble metal salts, in particular metal carbonates. The detergents, mainly of the anionic type, are, for example, metal salicylate, phenate, sulphonate or carboxylate soaps which form micelles in which the insoluble metal salt particles are kept in suspension. The usual overbased detergents intrinsically have a BN conventionally comprised between 150 and 700 mg of potash per gram of detergent.
    Part of the BN can also be provided by non-overbased or "neutral" detergents of BN typically less than 150 mg of potash per gram of detergent. Nevertheless, the Applicant has found that during the combustion of fuel oil, the neutral and / or overbased detergents present in the lubricant composition chemically deteriorated and therefore formed ash, also called residues or deposits that favored engine fouling , especially the marine engine.
    In order to reduce the ash content formed during the combustion of fuel oil, the applicant has replaced part of the detergents supplying the entire BN of the lubricating composition with compounds providing BN and forming no or little ash during the combustion of fuel oil. The Applicant has therefore developed lubricating compositions in which a portion of the detergents providing the BN of the lubricating composition is replaced by amino compounds. WO 2009/153453 discloses a cylinder lubricating composition having a BN greater than or equal to 40 milligrams of potash per gram of lubricant and comprising a base oil, an alkali metal or alkaline earth based detergent, overbased by carbonate metal salts , a neutral detergent and a fatty amine and / or oil-soluble fatty amine derivative having a BN of between 150 and 600 milligrams of potash per gram of lubricant. WO 2014/180843 describes a lubricating composition for a cylinder having a BN greater than or equal to 50 milligrams of potash per gram of lubricant comprising a base oil, a detergent based on alkaline or alkaline earth metals, overbased with carbonate metal salts, a neutral detergent and a fatty amine mixture having four amine units. EP 2486 113 discloses a marine engine lubricating oil comprising a monoamine comprising a base oil, a detergent and a disubstituted monoamine by a hydrogen atom or a hydrocarbon group having 1 to 50 carbon atoms.
    In the continuity of its investigations, the Applicant has surprisingly discovered that the amine compounds, usually used to replace part of the BN of the lubricating composition while decreasing the ash content formed during the combustion of fuel oil, also make it possible to prevent and / or to reduce the metallic losses of the parts of an engine, in particular of a marine engine, when these are in contact with acids resulting from the combustion of fuel oil.
    Thus, the applicant company has found that the use of one or more fatty amines soluble in a lubricating composition, the fatty amine being of formula (I):
    in which, R1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, • R2, R4 or R5 independently represents a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom chosen from nitrogen, sulfur or oxygen, • R3 represents a saturated or unsaturated, linear hydrocarbon-based group or branched, comprising one or more carbon atom (s), and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, preferably oxygen, • n is an integer greater than or equal to 1 , preferably between 1 and 10, more preferably between 1 and 6, even more preferably is chosen from 1, 2 or 3, can prevent and / or reduce p metal parts of an engine, preferably a marine engine.
    Fatty amines included in a lubricating composition are known as such in the applications WO 2009/153453 and WO 2014/180843 filed by the Applicant. The applicant has now discovered a new use of these fatty amines.
    A first subject of the invention relates to the use of one or more soluble fatty amines in a lubricating composition for preventing and / or reducing the metallic losses of parts of an engine, preferably of a marine engine, amine grasse is of formula (I): in which,
    R 1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom chosen from nitrogen, sulfur or oxygen, R 2, R 4 or R 5 represents independently, a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, • R3 represents a linear or branched saturated or unsaturated hydrocarbon group , comprising one or more carbon atoms, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, preferably oxygen, • n is an integer greater than or equal to 1, preferably between 1 and 10, more preferably between 1 and 6, even more preferably is selected from 1, 2 or 3.
    Without being bound to the theory, the Applicant has observed, surprisingly, that the fatty amines according to the invention make it possible not only to supply organic BN to the lubricating composition while providing no or little ash during the combustion of fuel oil but also prevent and / or reduce the metal losses of parts of an engine, especially in a marine engine, when they are brought into contact with the acids from the combustion of fuel oil. More specifically, the Applicant has unexpectedly discovered that these fatty amines soluble in a lubricating composition in the presence of a large excess of sulfuric acid make it possible to reduce and / or reduce the metallic losses of the parts directly in contact with said lubricant composition. and the large excess of sulfuric acid. This limitation and / or reduction of the metallic losses of the parts is probably due to the passivation of all or part of the surface of the metal parts by said fatty amines.
    For the purposes of the invention, the term "metallic losses of parts of an engine", the metal losses resulting from the attack of these parts by acids and not the metal losses generated by friction of a metal part on a other.
    Preferably, the fatty amine is of formula (I) in which: R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 22 carbon atoms, preferably from 14 to 22 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, and / or • R2, R4 or R5 independently represents a hydrogen atom; a saturated or unsaturated, linear or branched alkyl group comprising between 1 and 22 carbon atoms, preferably between 14 and 22 carbon atoms, more preferably between 16 and 22 carbon atoms; or a group (R6-0) pH in which Rf) is a saturated, linear or branched alkyl group comprising at least 2 carbon atoms, preferably between 2 and 6 carbon atoms, more preferably between 2 and 4 carbon atoms and p represents an integer greater than or equal to 1, preferably between 1 and 6, more preferably between 1 and 4, and / or • R3 represents a saturated or unsaturated, linear or branched alkyl group comprising between 2 and 6 atoms carbon, preferably between 2 and 4 carbon atoms.
    More preferentially, the fatty amine is of formula (I) in which: n is equal to 1, 2 or 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 20 carbon atoms, preferably from 14 to 20 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen; R2 independently represents a hydrogen atom or a saturated, linear or branched alkyl group comprising 1 to 20 carbon atoms, preferably 16 to 20 carbon atoms, more preferably 16 to 18 carbon atoms, • R3 represents a saturated and linear alkyl group comprising between 2 and 6 carbon atoms, preferably between 2 and 6 carbon atoms, 4 carbon atoms, • R4 and R5 represent a hydrogen atom or a methyl group, preferably a hydrogen atom.
    Advantageously, the fatty amine is of formula (I) in which: n is equal to 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 20 carbon atoms, preferably from 14 to 20 carbon atoms, more preferably 16 to 20 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, • R2 independently represents a hydrogen atom or a linear saturated alkyl group or branched, comprising from 16 to 18 carbon atoms, • R3 represents an ethyl or propyl group, • R4 and R5 represent a hydrogen atom.
    More preferentially, the fatty amine is also of formula (I) in which: n is equal to 1, 2 or 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 20 carbon atoms preferably, from 16 to 20 carbon atoms, R 2, R 4 and R 5 independently represent a hydrogen atom or a group (R 6 -O) pH in which R 6 is a linear saturated alkyl group comprising between 2 and 6 atoms of carbon, more preferably between 2 and 4 carbon atoms and p representing an integer between 1 and 6, more preferably between 1 and 4, • R3 represents a saturated and linear alkyl group, comprising between 2 and 6 carbon atoms, preferably between 2 and 4 carbon atoms.
    Advantageously, the fatty amine is also of formula (I) in which: n is equal to 3, R 1 represents a linear or branched, saturated or unsaturated alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to to 20 carbon atoms, R2, R4 and R5 independently represents a hydrogen atom or a group (R6-O) pH in which R6 is a linear saturated alkyl group comprising between 2 and 4 carbon atoms and p representing an integer between 1 and 4, • R3 represents an ethyl or propyl group.
    According to a particular embodiment of the invention, the use of fatty amine of formula (I) makes it possible to prevent and / or reduce the metallic losses of parts in a marine engine, two times or four times during the combustion of fuel. any type of fuel.
    Preferably, the use of fatty amine of formula (I) makes it possible to prevent and / or reduce the metallic losses of the parts in the hot parts, in particular the segment-piston-jacket zone (SPC), of a marine engine, two or four times, when burning any type of fuel oil.
    Preferably, the fuel oil has a sulfur content of less than 3.5% by weight relative to the total weight of the fuel oil.
    Detailed description of the invention.
    Fatty amine
    A first subject of the invention relates to the use of one or more soluble fatty amines in a lubricating composition for preventing and / or reducing the metallic losses of parts of an engine, preferably of a marine engine, amine fat is of formula (I):
    in which, R1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, • R2, R4 or R5 independently represents a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, • R3 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising one or more carbon atom (s), and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, preferably oxygen, • n is an integer greater than or equal to 1, preferably between 1 and 10, more preferably between 1 and 6, still more preferably is selected from 1, 2 or 3.
    The term "fatty amine" according to the invention is understood to mean an amine of formula (I) comprising one or more hydrocarbon groups, saturated or unsaturated, linear or branched, and optionally comprising at least one heteroatom chosen from nitrogen, sulfur or oxygen, preferably oxygen.
    By "several fatty amines" according to the invention is meant a mixture of fatty amines at least one fatty amine of formula (I).
    Preferably, the fatty amine is of formula (I) in which: R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 22 carbon atoms, preferably from 14 to 22 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, and / or • R2, R4 or R5 independently represents a hydrogen atom; a saturated or unsaturated, linear or branched alkyl group comprising between 1 and 22 carbon atoms, preferably between 14 and 22 carbon atoms, more preferably between 16 and 22 carbon atoms; or a group (R6-O) pH in which R6 is a saturated, linear or branched alkyl group comprising at least 2 carbon atoms, preferably between 2 and 6 carbon atoms, more preferably between 2 and 4 carbon atoms, and p represents an integer greater than or equal to 1, preferably between 1 and 6, more preferably between 1 and 4, and / or • R3 represents a linear or branched, saturated or unsaturated alkyl group comprising between 2 and 6 carbon atoms. carbon, preferably between 2 and 4 carbon atoms.
    Advantageously, the fatty amine is of formula (I) in which: n is equal to 1, 2 or 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to 20 carbon atoms, and optionally at least one heteroatom chosen from nitrogen, sulfur or oxygen; R 2 independently represents a hydrogen atom or a saturated, linear or branched alkyl group comprising from 1 to to 20 carbon atoms, more preferably 16 to 20 carbon atoms, more preferably 16 to 18 carbon atoms, • R-3 represents a saturated and linear alkyl group, comprising between 2 and 6 carbon atoms, preferably between 2 and 4 carbon atoms, • R4 and R5 represent a hydrogen atom or a methyl group, preferably a hydrogen atom.
    In particular, the fatty amine is of formula (I) in which: n is equal to 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to to 20 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, R2 independently represents a hydrogen atom or a linear or branched, saturated alkyl group comprising from 16 to 18 atoms of carbon, • R3 represents an ethyl or propyl group, • R4 and R5 represent a hydrogen atom.
    Advantageously, the fatty amine is of formula (I) in which: n is equal to 1, 2 or 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 20 carbon atoms, preferably, from 16 to 20 carbon atoms, R2, R4 and R5 independently represent a hydrogen atom or a group (R6-O) pH in which Rf) is a linear, saturated alkyl group comprising between 2 and 6 carbon atoms; carbon, more preferably between 2 and 4 carbon atoms and p representing an integer between 1 and 6, more preferably between 1 and 4, • R3 represents a saturated and linear alkyl group, comprising between 2 and 6 carbon atoms, preferably between 2 and 4 carbon atoms.
    In particular, the fatty amine is of formula (I) in which: n is equal to 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to to 20 carbon atoms, R2, R4 and R5 independently represents a hydrogen atom or a group (R6-O) pH in which R6 is a linear saturated alkyl group comprising between 2 and 4 carbon atoms and p representing an integer between 1 and 4, • R3 represents an ethyl or propyl group.
    In general, the fatty amines according to the invention are mainly obtained from carboxylic acids. These acids are dehydrated in the presence of ammonia to give nitriles, and then undergo catalytic hydrogenation to lead in particular to fatty amines.
    For the purposes of the invention, the fatty amine of formula (I) is obtained from at least one carboxylic acid, preferably at least one fatty acid.
    Within the meaning of the invention, the alkyl group of the fatty amine has a number of carbon atoms corresponding to the number of carbon atoms of the carbon chain of the carboxylic acid, preferably corresponding to the number of carbon atoms. carbon of the carbon chain of the fatty acid
    Within the meaning of the invention, the same fatty amine of formula (I) may be substituted by several alkyl groups obtained from several identical or different carboxylic acids, preferably obtained from several identical or different fatty acids.
    According to a particular embodiment of the invention, the alkyl group is obtained from fatty acid chosen from caprylic, pelargonic, capric, undecylenic, lauric, tridecylenic, myristic, pentadecyl, palmitic, margaric, stearic and nonadecyl acids. arachic, henicosanoic, behenic, tricosanoic, lignoceric, pentacosanoic, cerotic, heptacosanoic, montanic, nonacosanoic, melissic, hentriacontanoic, laceroic, and their derivatives or unsaturated fatty acids such as palmitoleic acid, oleic acid, erucic acid, nervonic acid, linoleic acid, -linolenic, c-linolenic, di-homo-c-linolenic, arachidonic, eicosapentaenoic, docosahexanoic, and their derivatives.
    Preferably, the fatty acids are derived from the hydrolysis of triglycerides present in vegetable and animal oils, such as coconut oil, palm oil, olive oil, peanut oil, rapeseed oil, sunflower oil, soya oil, of cotton, flax, beef tallow. Natural oils may have been genetically modified to enrich their content of certain fatty acids, for example rapeseed oil or oleic sunflower oil.
    In general, the fatty amine of formula (I) according to the invention is preferably obtained from natural resources, plant or animal. Treatments for producing fatty amines from natural oils can lead to mixtures of primary, secondary and tertiary polyamines.
    According to one particular embodiment of the invention, when several fatty amines are used to prevent and / or reduce the metallic losses of the parts of an engine, said fatty amines form a mixture of fatty amines comprising in variable proportions, all or a part of the compounds corresponding to the following formulas (Ia), (Ib) and (Ic):
    (the) ,
    (lb),
    wherein R1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, R 2, R4 or R5 independently represents a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, • R-3 represents a grouping saturated or unsaturated hydrocarbon, linear or branched, comprising one or more carbon atom (s), and optionally comprising at least one heteroatom chosen from nitrogen, sulfur or oxygen, preferably oxygen,
    The preferences and advantages for the definitions of the groups R 1, R 2, R 3, R 4, R 5 and R 6 of the fatty amines of formulas (Ia), (Ib) and (Ie) are as defined above for the fatty amine of formula (I) according to the invention.
    According to another particular embodiment, the mixture of fatty amines is in a purified form, that is to say comprising mainly a single type of amine of formula (Ia), (Ib) or (Ie), by Mostly diamines of formula (Ia), triamines of formula (Ib) or predominantly tetramines of formula (Ia). In particular, the mixture of fatty amines comprises predominantly tetramines of formula (Ic).
    According to one particular embodiment of the invention, the mixture of fatty amines comprises mainly: diamines of formula (Ia), or triamines of formula (Ib), or tetramines of formula (Ia), in which, the groups R1, R2, R3, R4, R5 and Rf) are as defined above.
    In another embodiment of the invention, the fatty amine mixture mainly comprises diamines of formula (Ia) in which: R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 20 carbon atoms, carbon, preferably from 14 to 20 carbon atoms, more preferably from 16 to 20 carbon atoms, R 2 represents a saturated, linear or branched alkyl group comprising from 1 to 5 carbon atoms, preferably from 1 to 3 carbon atoms, carbon, more preferably a methyl group, • R3 represents an ethyl or propyl group, • R4 and R5 independently represent a saturated alkyl group, linear or branched, comprising from 1 to 5 carbon atoms, preferably from 1 to 3 carbon atoms , more preferably a methyl group.
    Preferably, the mixture of fatty amines predominantly comprises diamines of formula R 1 - [(NR 2) -R 3] -NH 2 (IIa), triamines of formula R 1 - [(NR 2) -R 3] 2 -NH 2 (IIb), or tetramines of formula R1 - [(NR2) -R3] 3 -NH2 (Ile), wherein: • R1 or R2 represents at least one alkyl group, saturated or unsaturated, obtained from a fatty acid derived from tallow fat, or soybean oil, or coconut oil, or (oleic) sunflower oil, and • R3 represents a linear or branched, saturated or unsaturated hydrocarbon group, comprising at least 2 carbon atoms.
    In the context of the invention, when R 1 or R 2 represents a saturated alkyl group, said saturated alkyl is obtained from a saturated fatty acid or from a hydrogenated unsaturated fatty acid, in particular from the whole of these double bonds.
    Advantageously, the mixture of fatty amines comprising predominantly tetramines of formula R1 - [(NR2) -R3] 3 -NH2 (Ile) is in the form of: at least one fatty amine of formula (IIc) in which Ri represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 16 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms of at least one fatty amine of formula (IIe) in which R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising at least 18 carbon atoms; carbon; R2 represents a hydrogen atom; and R 3 represents a saturated, linear alkyl group comprising from 2 to 6 carbon atoms, and at least one fatty amine of formula (II) in which R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising at least 20 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms.
    In particular, the mixture of fatty amines comprising predominantly tetramines of formula R1 - [(NR2) -R3] 3 -NH2 (Ile) is in the form of: at least one fatty amine of formula (IIc) in which R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 14 to 16 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms, of at least one fatty amine of formula (IIc) in which R1 represents a linear or branched, saturated or unsaturated alkyl group comprising at least 18 atoms; of carbon ; R2 represents a hydrogen atom; and R 3 represents a saturated, linear alkyl group comprising from 2 to 6 carbon atoms, and at least one fatty amine of formula (II) in which R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising at least 20 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms, the sum of the content by weight of said fatty amines of formula (IIc) being greater than 90% relative to the weight of said mixture of fatty amines.
    Advantageously, the mixture of fatty amines comprising predominantly tetramines of formula R 1 - [(NR 2) -R 3] 3 -NH 2 (II) is also in the form of: at least one fatty amine of formula (II) in which R 1 represents a linear or branched unsaturated alkyl group comprising from 16 to 20 carbon atoms, preferably from 18 to 20 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms and from at least one fatty amine of formula (IIc) in which R1 represents a linear or branched saturated alkyl group comprising from 16 to 20 carbon atoms preferably from 18 to 20 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms.
    In particular, the mixture of fatty amines comprising predominantly tetramines of formula R1 - [(NR2) -R3] 3 -NH2 (Ile) is in the form of: at least one fatty amine of formula (IIc) in which R 1 represents a linear or branched unsaturated alkyl group comprising from 16 to 20 carbon atoms, preferably from 18 to 20 carbon atoms; R2 represents a hydrogen atom; and R 3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms, of at least one fatty amine of formula (II) in which R 1 represents a linear or branched saturated alkyl group comprising from 16 to 20 carbon atoms preferably from 18 to 20 carbon atoms; R2 represents a hydrogen atom; and R3 represents a linear saturated alkyl group comprising from 2 to 6 carbon atoms, the sum of the content by weight of said fatty amines of formula (IIc) being greater than 90% relative to the weight of said mixture of fatty amines.
    Preferably, the fatty amine mixture does not comprise fatty amines other than fatty amines having the formula (IIc).
    According to a particular embodiment of the invention, when a single fatty amine is used to prevent and / or reduce the metallic losses of the parts of an engine, said fatty amine corresponds to one of the following formulas: a diamine of formula (IIa), or - a triamine of formula (IIb), or - a tetramine of formula (IIc), in which: • Ri represents a linear or branched saturated hydrocarbon group comprising at least 14 carbon atoms, • R -2 independently represents a hydrogen atom or a saturated hydrocarbon group, linear or branched, comprising at least 14 carbon atoms, • R3 represents a linear saturated hydrocarbon group comprising at least 2 carbon atoms.
    In this embodiment, the fatty amine is preferably a tetramine of formula (IIc) in which, R1 represents a linear or branched saturated alkyl group, comprising between 14 and 18 carbon atoms, R2 represents independently an atom of hydrogen or a saturated hydrocarbon group, linear or branched, comprising between 14 and 18 carbon atoms, • R3 represents a linear saturated hydrocarbon group comprising between 2 and 6 carbon atoms.
    In this embodiment, the fatty amine is advantageously a tetramine of formula (IIc) in which: R 1 represents a linear or branched saturated alkyl group, comprising between 16 and 18 carbon atoms, R 2 independently represents an atom of hydrogen or a saturated hydrocarbon group, linear or branched, comprising between 16 and 18 carbon atoms, • R3 represents an ethyl or propyl group.
    Lubricating Composition The fatty amine or the mixture of fatty amines according to the invention for preventing and / or reducing the metallic losses of the parts of an engine, preferably of a marine engine, is present in a lubricating composition. Said lubricant composition comprises: at least one base oil, preferably a lubricating base oil for a marine engine; at least one detergent based on alkali or alkaline earth metals, overbased with carbonate metal salts.
    Preferably, the lubricating composition has a BN determined according to ASTM D-2896 greater than or equal to 15 milligrams of potash per gram of lubricant, more preferably greater than or equal to 40 milligrams.
    Advantageously, the lubricating composition has a BN determined according to the ASTM D-2896 standard of between 40 and 120 milligrams of potash per gram of lubricant, preferably between 50 and 100 milligrams of potash per gram of lubricant.
    Advantageously, the lubricating composition also has a BN determined according to the ASTM D-2896 standard of between 15 and 40 milligrams of potash per gram of lubricant, preferably between 20 and 40 milligrams of potash per gram of lubricant.
    According to one embodiment of the invention, the mass percentage of fatty amine relative to the total weight of the cylinder lubricant is chosen so that the BN supplied by this fatty amine represents a contribution of at least 2 milligrams of potassium hydroxide. per gram of total BN lubricant of said cylinder lubricant, preferably at least 5 milligrams of potash per gram of lubricant to the total BN of said cylinder lubricant.
    The proportion of BN supplied by a fatty amine in the lubricant cylinder according to the invention (in milligram of potash per gram of finished lubricant, or "points" of BN) is calculated from its intrinsic BN measured according to the ASTM D standard. -2896 and its mass percentage in the finished lubricant: BN amine lub = x. B N amine / 100 BN amine lub = contribution of amine to the BN of the finished lubricant x = mass% of the amine in the finished lubricant BN amine = intrinsic BN of the amine alone (ASTM D-2896).
    According to one embodiment of the invention, the mass percentage of fatty amine relative to the total weight of the cylinder lubricant is chosen so that the BN supplied by this fatty amine represents a contribution of 2 to 30 milligrams of potassium hydroxide per gram. gram of lubricant, more preferably from 5 to 25 milligrams of potash per gram of lubricant to the total BN of said lubricant cylinder.
    In another embodiment of the invention, the fatty amine represents from 0.5 to 10%, preferably from 0.5 to 8% by weight relative to the total weight of the lubricating composition.
    Preferably, the lubricating composition further comprises at least one neutral detergent. As for the detergents used in the lubricant compositions according to the present invention, these are well known to those skilled in the art.
    According to a particular embodiment of the invention, the detergents commonly used in the formulation of lubricating compositions are typically anionic compounds comprising a long lipophilic hydrocarbon chain and a hydrophilic head. The associated cation is typically a metal cation of an alkali or alkaline earth metal.
    The detergents are preferably chosen from alkali metal or alkaline earth metal salts of carboxylic acids, sulphonates, salicylates and naphthenates, as well as the salts of phenates.
    The alkaline and alkaline earth metals are preferably calcium, magnesium, sodium or barium.
    These metal salts may contain the metal in an approximately stoichiometric amount. In this case, we speak of non-overbased or "neutral" detergents, although they also bring some basicity. These "neutral" detergents typically have a BN, measured according to ASTM D2896, less than 150 mg KOH / g, or less than 100, or even less than 80 mg KOH / g.
    This type of so-called neutral detergents may contribute in part to B N lubricants according to the present invention. For example, neutral detergents of carboxylates, sulphonates, salicylates, phenates, alkali metal and alkaline earth metal naphthenates, for example calcium, sodium, magnesium or barium, will be used.
    When the metal is in excess (in an amount greater than the stoichiometric amount), we are dealing with so-called overbased detergents. Their BN is high, greater than 150 mg KOH / g, typically between 200 and 700 mg KOH / g, generally between 250 and 450 mg KOH / g.
    The excess metal providing the overbased detergent character is in the form of oil insoluble metal salts, for example carbonate, hydroxide, oxalate, acetate, glutamate, preferably carbonate.
    In the same overbased detergent, the metals of these insoluble salts may be the same as those of the oil-soluble detergents or may be different. They are preferably selected from calcium, magnesium, sodium or barium.
    The overbased detergents are thus in the form of micelles composed of insoluble metal salts maintained in suspension in the lubricating composition by the detergents in the form of oil-soluble metal salts.
    These micelles may contain one or more types of insoluble metal salts, stabilized by one or more detergent types.
    Overbased detergents with a single type of detergent soluble metal salt will generally be named after the nature of the hydrophobic chain of the latter detergent.
    Thus, they will be called carboxylate, phenate, salicylate, sulfonate, naphthenate depending on whether the detergent is a carboxylate, phenate, salicylate, sulfonate, or naphthenate, respectively.
    The overbased detergents will be said to be of mixed type if the micelles comprise several types of detergents, different from each other by the nature of their hydrophobic chain.
    For use in the lubricating compositions according to the present invention, the oil-soluble metal salts will preferably be carboxylates, phenates, sulphonates, salicylates, and mixed detergents phenate-sulphonate and / or salicylates of calcium, magnesium, sodium or barium.
    The insoluble metal salts providing the overbased character are alkali and alkaline earth metal carbonates, preferentially calcium carbonate.
    The overbased detergents used in the lubricating compositions according to the present invention are preferably carboxylates, phenates, sulphonates, salicylates and mixed detergents phenates-sulphonates-salicylates, overbased with calcium carbonate.
    According to a particular embodiment of the invention, the base oil included in the lubricating composition is selected from oils of mineral, synthetic or vegetable origin and mixtures thereof.
    The mineral or synthetic oils generally used in the application belong to one of the classes defined in the API classification as summarized in the table below.
    The Group 1 mineral oils can be obtained by distillation of selected naphthenic or paraffinic crudes and then purification of these distillates by processes such as solvent extraction, solvent or catalytic dewaxing, hydrotreating or hydrogenation.
    The oils of Groups 2 and 3 are obtained by more severe purification methods, for example a combination among hydro-treatment, hydrocracking, hydrogenation and catalytic dewaxing.
    Examples of Group 4 and 5 synthetic bases include poly-alpha olefins, polybutenes, polyisobutenes, alkylbenzenes.
    These base oils can be used alone or as a mixture. A mineral oil can be combined with a synthetic oil.
    Cylinder oils for 2-stroke marine diesel engines have a SAE-40 SAE-40 viscometric grade, typically SAE-50 equivalent to a kinematic viscosity at 100 ° C of 16.3 to 21.9 mm2 / s.
    Grade 40 oils have a kinematic viscosity at 100 ° C of between 12.5 and 16.3 mm 2 / s.
    Grade 50 oils have a kinematic viscosity at 100 ° C of between 16.3 and 21.9 mm 2 / s.
    Grade 60 oils have a kinematic viscosity at 100 ° C between 21.9 and 26.1 V.
    According to the uses of the profession, it is preferred to formulate cylinder oils for 2-stroke marine diesel engines having a kinematic viscosity at 100 ° C. of between 18 and 21.5, preferably between 19 and 21.5 mm / s.
    This viscosity can be obtained by mixing additives and base oils, for example containing Group 1 mineral bases such as Neutral Solvent (for example 500NS or 600 NS) and Brightstock bases. Any other combination of mineral, synthetic or vegetable bases having, in admixture with the additives, a viscosity compatible with the grade SAE-50 may be used.
    Typically, a conventional cylinder lubricant formulation for slow 2-cycle marine diesel engines is SAE 40 to SAE60, preferably SAE50 (SA37 J300) and includes at least 50% by weight of original lubricating base oil. mineral and / or synthetic, suitable for use in a marine engine, for example of API Group 1, that is to say obtained by distillation of selected crudes and purification of these distillates by processes such as solvent extraction , solvent or catalytic dewaxing, hydrotreatment or hydrogenation. Their Viscosity Index (VI) is between 80 and 120; their sulfur content is greater than 0.03% and their saturated content is less than 90%.
    According to a particular embodiment of the invention, the lubricant composition may further comprise one or more thickening additives whose role is to increase the viscosity of the composition, hot or cold, or by improving additives of index viscosity (VI).
    Preferably, these additives are most often low molecular weight polymers of the order of 2,000 to 50,000 daltons (Mn).
    They may be chosen from PIBs (of the order of 2000 daltons), polyacrylate or poly methacrylates (of the order of 30,000 daltons), olefin copolymers, olefin and alpha olefin copolymers, EPDM, polybutenes and polyolefins. high molecular weight (viscosity 100 ° C> 150), Styrene-Olefin copolymers, hydrogenated or not.
    According to a particular embodiment of the invention, the base oil (s) included in the lubricating composition according to the invention may be partially or totally substituted by these additives. As a result, the polymers used to partially or totally substitute one or more of the base oils are preferably the aforementioned thickeners of the PIB type (for example marketed under the name Indopol H2100).
    According to a particular embodiment of the invention, the lubricating composition may further comprise at least one antiwear additive.
    Preferably, the anti-wear additive is zinc di thiophosphate or DTPZn. This category also contains various phosphorus, sulfur, nitrogen, chlorine and boron compounds.
    There is a wide variety of anti-wear additives, but the most used category is that of phospho-sulfur-containing additives such as metal alkylthiophosphates, in particular zinc alkylthiophosphates, and more specifically zinc dialkyldithiophosphates or DTPZn.
    Amine phosphates, polysulfides, especially sulfur-containing olefins, are also commonly used antiwear additives.
    Lubricating compositions containing nitrogenous and sulfur-containing anti-wear and extreme pressure additives, such as, for example, metal dithiocarbamates, in particular molybdenum dithiocarbamate, are also usually encountered in lubricating compositions. Glycerol esters are also anti-wear additives. Mention may be made, for example, of mono, di and trioleates, monopalmitates and monomyristates.
    According to a particular embodiment of the invention, the lubricating composition may further comprise at least one dispersant.
    Dispersants are well-known additives used in the formulation of lubricating composition, especially for application in the marine field. Their primary role is to maintain in suspension the particles present initially or appearing in the lubricant composition during its use in the engine. They prevent their agglomeration by playing on steric hindrance. They can also have a synergistic effect on the neutralization.
    The dispersants used as lubricant additives typically contain a polar group, associated with a relatively long hydrocarbon chain, generally containing from 50 to 400 carbon atoms. The polar group typically contains at least one nitrogen, oxygen or phosphorus element.
    The compounds derived from succinic acid are dispersants particularly used as lubrication additives. Especially succinimides, obtained by condensation of succinic anhydrides and amines, succinic esters obtained by condensation of succinic anhydrides and alcohols or polyols.
    These compounds can then be treated with various compounds including sulfur, oxygen, formaldehyde, carboxylic acids and compounds containing boron or zinc to produce, for example, borated succinimides or zinc-blocked succinimides.
    Mannich bases, obtained by polycondensation of phenols substituted with alkyl groups, formaldehyde and primary or secondary amines, are also compounds used as dispersants in lubricants.
    It is possible to use a dispersant in the family of succinimide PIBs, for example borated or blocked with zinc.
    According to one particular embodiment of the invention, the lubricating composition may furthermore comprise all types of functional additives adapted to their use, for example anti-foam additives to counteract the effect of detergents, which may be, for example, polar polymers such as polymethylsiloxanes, polyacrylates, anti-oxidant and / or anti-rust additives, for example metal organo-detergents or thiadiazoles. These are known to those skilled in the art.
    According to the present invention, the compositions of the lubricants described refer to the compounds taken separately before mixing, it being understood that said compounds may or may not retain the same chemical form before and after mixing. Preferably, the lubricants according to the present invention obtained by mixing the compounds taken separately are not in the form of emulsion or microemulsion.
    Motor The use of one or more fatty amines according to the invention soluble in a lubricant composition makes it possible to prevent and / or reduce the metallic losses of the parts of an engine.
    According to a particular embodiment of the invention, the use of one or more fatty amines makes it possible to prevent and / or reduce the metallic losses of the parts in a marine engine, two times or four times during the combustion of any type of fuel.
    According to one particular embodiment of the invention, the use of one or more fatty amines according to the invention makes it possible to prevent and / or reduce the metallic losses of the parts in the hot parts, in particular the SPC zone, of a marine engine, two-stroke or four-stroke, when burning any type of fuel oil.
    According to a particular embodiment of the invention, the fuel oil has a sulfur content of less than 3.5% by weight relative to the total weight of the fuel oil.
    The various embodiments, variants, preferences and advantages described above may be taken separately or in combination for the implementation of the first subject of the invention.
    Process
    A second subject of the invention covers a method for preventing and / or reducing the metallic losses of parts of an engine, preferably of a marine engine in which said parts are brought into contact with one or more soluble fatty amines in a lubricating composition of formula (I):
    in which, R1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, • R2, R4 or R5 independently represents a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, • R-3 represents a saturated hydrocarbon group or unsaturated, linear or branched, comprising one or more carbon atom (s), and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, preferably oxygen, • n is a higher integer or equal to 1, preferably between 1 and 10, more preferably between 1 and 6, still more preferably is selected from 1, 2 or 3.
    The various embodiments, preferences, advantages, variants described for the first subject of the invention covering the use of one or more soluble fatty amines in a lubricating composition for preventing and / or reducing the metallic losses of the parts an engine, preferably a marine engine, apply separately or in combination with the second subject of the invention covering the method described above. The invention is illustrated by the following examples given without limitation.
    Experimental protocol for measurements of metal part losses
    200 g of the lubricating composition comprising one or more fatty amines according to the invention are introduced into a 700 ml test tube and this test piece is heated at 60 ° C. with vigorous stirring for a period of approximately 30 minutes.
    A cast iron plate, previously sanded, cleaned and weighed, is immersed in the test tube thus heated and agitated, then a quantity of sulfuric acid diluted to 50% is gradually added during 1 h 30 in order to neutralize all or part of the total BN. of said lubricating composition. The amount of 50% diluted sulfuric acid added to the lubricating composition is calculated as a function of the number of BN points to be neutralized. The rate of addition of sulfuric acid diluted to 50% is calculated as a function of the total amount of sulfuric acid to be added over a period of 1h30.
    The lubricating composition thus acidified and comprising the plate is subsequently stirred for an additional 30 minutes to ensure that the BN neutralization reaction is complete.
    The plate immersed in the acidified lubricating composition is then removed from the test piece and weighed to determine the metal losses of said cast iron plate due to sulfuric acid attack.
    EXAMPLE
    Evaluation of metallic losses of a metal part placed in contact with the fatty amines according to the invention and with sulfuric acid This is to evaluate the metallic losses of a metal part directly put in contact with the sulfuric acid and with fatty amines according to the invention contained in a lubricating composition.
    For this purpose, various lubricating compositions have been prepared from the following compounds: a lubricating base oil comprising a mixture of mineral oils of group I and / or II, in particular Brightstock type oils, a detergent package, a fatty amine 1 comprising predominantly tetramines of formula (I), - a fatty amine 2 comprising predominantly tetramines of formula (I), - a fatty amine 3 comprising predominantly diamines of formula (I), - a fatty amine 4 comprising predominantly triamines of formula (I), - a fatty amine comprising predominantly tetramines of formula (I).
    Compositions Li to L7 according to the invention are described in Table I and a control lubricant composition L§ comprising only a base oil and a detergent package; the percentages given correspond to mass percentages.
    Table I
    The results obtained concerning the metallic losses of the parts brought into contact with sulfuric acid and respectively with the lubricant compositions Li to Lg are described in Table II.
    Table II
    It is observed that the presence of fatty amines according to the invention contained in compositions Li at L7 and L9 at Lu makes it possible to significantly reduce or even to avoid the metallic losses of a part directly put in contact with sulfuric acid and this regardless of the content of fatty amines in the lubricating composition, in contrast to the control composition which does not comprise fatty amines according to the invention. In particular, the metallic losses of the parts do not exceed 4 mg when these parts are immersed in an acid medium and respectively in the presence of different types of fatty amines according to the invention contained in the lubricating compositions, in contrast to the metallic losses of the parts. contacted with sulfuric acid and a lubricating composition not comprising fatty amines according to the invention which exceed 80 mg.
    It is also a question of evaluating the metallic losses of a metal part directly put in contact with fatty amines according to the invention contained in a lubricating composition and with a large excess of sulfuric acid in order to demonstrate that the reduction of losses metal under such conditions is not due to the neutralization of sulfuric acid by said fatty amines but comes from the passivation of all or part of the surface of the metal parts by said fatty amines.
    For this, two metal parts were respectively immersed in the lubricant compositions L4 and L§ in the presence of a large excess of sulfuric acid. The results obtained concerning the metallic losses of the parts brought into contact with a large excess of sulfuric acid and respectively with the lubricating compositions L4 and Lg are described in Table III.
    The test for evaluating the metallic losses of a metal part directly contacted with fatty amines according to the invention contained in a lubricating composition and with a large excess of sulfuric acid was carried out according to the experimental protocol for the measurements. metallic losses of metal part described above. In this test, the amount of sulfuric acid diluted to 50% introduced into the lubricant composition according to the invention was calculated so as to neutralize 150% of the total BN of the lubricating composition according to Table III.
    It is observed that even in the presence of a large excess of sulfuric acid, the metal part loses little material, that is to say it loses 7 mg when in contact with fatty amines according to the invention contained in a lubricating composition, unlike a metal part placed in contact with a lubricating composition not comprising fatty amines according to the invention for which the metal losses rise above 115 mg. Therefore, it is clearly demonstrated that the use of at least one fatty amine and / or fatty amine derivative contained in a lubricant composition can significantly reduce or even avoid metal losses of a piece of a engine, especially a marine engine, when it is in contact with an acidic medium.
    权利要求:
    Claims (10)
    [1" id="c-fr-0001]
    1. Using one or more soluble fatty amines in a lubricating composition to prevent and / or reduce the metallic losses of parts of an engine, preferably of a marine engine, the fatty amine is of formula (I):

    in which, R1 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising at least 12 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, • R2, R4 or R5 independently represents a hydrogen atom or a saturated or unsaturated hydrocarbon group, linear or branched, and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, • R3 represents a saturated or unsaturated hydrocarbon group, linear or branched, comprising one or more carbon atom (s), and optionally comprising at least one heteroatom selected from nitrogen, sulfur or oxygen, preferably oxygen, • n is an integer greater than or equal to 1, preferably between 1 and 10, more preferably between 1 and 6, still more preferably is selected from 1, 2 or 3.
    [2" id="c-fr-0002]
    2. Use according to claim 1, wherein: R 1 represents a linear or branched, saturated or unsaturated alkyl group comprising from 12 to 22 carbon atoms, preferably from 14 to 22 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, and / or • R2, R4 or R5 independently represents a hydrogen atom; a saturated or unsaturated, linear or branched alkyl group comprising between 1 and 22 carbon atoms, preferably between 14 and 22 carbon atoms, more preferably between 16 and 22 carbon atoms; or a group (R6-O) pH in which R6 is a saturated, linear or branched alkyl group comprising at least 2 carbon atoms, preferably between 2 and 6 carbon atoms, more preferably between 2 and 4 carbon atoms, and p represents an integer greater than or equal to 1, preferably between 1 and 6, more preferably between 1 and 4, and / or • R3 represents a linear or branched, saturated or unsaturated alkyl group comprising between 2 and 6 carbon atoms. carbon, preferably between 2 and 4 carbon atoms.
    [3" id="c-fr-0003]
    3. Use according to claim 1 or 2, wherein: n is equal to 1, 2 or 3, R 1 represents a saturated or unsaturated, linear or branched alkyl group comprising from 12 to 20 carbon atoms, preferably from 14 to 20 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen; R2 independently represents a hydrogen atom or a saturated, linear or branched alkyl group comprising from 1 to 20 carbon atoms, preferably from 16 to 20 carbon atoms, more preferably from 16 to 18 carbon atoms, • R3 represents a saturated and linear alkyl group comprising between 2 and 6 carbon atoms, preferably between 2 and 4 carbon atoms, carbon, • R4 and R5 represent a hydrogen atom or a methyl group, preferably a hydrogen atom.
    [4" id="c-fr-0004]
    4. Use according to claim 3, wherein: n is equal to 3, R 1 represents a linear or branched, saturated or unsaturated alkyl group comprising from 12 to 20 carbon atoms, preferably from 14 to 20 carbon atoms. more preferably from 16 to 20 carbon atoms, and optionally at least one heteroatom selected from nitrogen, sulfur or oxygen, R 2 independently represents a hydrogen atom or a saturated, linear or branched alkyl group , comprising from 16 to 18 carbon atoms, • R3 represents an ethyl or propyl group, • R4 and R5 represent a hydrogen atom.
    [5" id="c-fr-0005]
    5. Use according to claim 1 or 2, wherein: n is equal to 1, 2 or 3, R 1 represents a linear or branched, saturated or unsaturated alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to 20 carbon atoms, • R2, R4 and R5 independently represents a hydrogen atom or a group (R6-0) pH in which Rf) is a linear saturated alkyl group comprising between 2 and 6 carbon atoms, more preferably between 2 and 4 carbon atoms and p representing an integer between 1 and 6, more preferably between 1 and 4, • R3 represents a saturated and linear alkyl group, comprising between 2 and 6 carbon atoms, preferably between 2 and 4 carbon atoms.
    [6" id="c-fr-0006]
    6. Use according to claim 5, wherein: n is equal to 3, R 1 represents a linear or branched, saturated or unsaturated alkyl group comprising from 14 to 20 carbon atoms, preferably from 16 to 20 carbon atoms. R2, R4 and R5 independently represent a hydrogen atom or a group (R6-0) pH in which Rf) is a linear saturated alkyl group comprising between 2 and 4 carbon atoms and p represents an integer between 1 and 4, • R3 represents an ethyl or propyl group.
    [7" id="c-fr-0007]
    7. Use according to any one of the preceding claims, wherein the fatty amine represents from 0.5 to 10%, preferably from 0.5 to 8% by weight relative to the total weight of the lubricating composition.
    [8" id="c-fr-0008]
    8. Use according to any preceding claim for preventing and / or reducing metal losses of parts in a marine engine, two-stroke or four-stroke during the combustion of any type of fuel oil.
    [9" id="c-fr-0009]
    9. Use according to any one of the preceding claims, for preventing and / or reducing the metal losses of the parts in the hot parts, including the SPC zone, of a marine engine, two times or four times, during the combustion of any type of fuel.
    [10" id="c-fr-0010]
    10. Use according to any one of the preceding claims, wherein the fuel oil has a sulfur content of less than 3.5% by weight relative to the total weight of the fuel oil.
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    同族专利:
    公开号 | 公开日
    HK1251606A1|2019-02-01|
    EP3331975A1|2018-06-13|
    KR20180036723A|2018-04-09|
    CN107922876A|2018-04-17|
    BR112018002388A2|2018-09-18|
    US20180223218A1|2018-08-09|
    RU2018103966A|2019-08-02|
    JP6833813B2|2021-02-24|
    JP2018522131A|2018-08-09|
    CN107922876B|2020-11-03|
    RU2018103966A3|2019-10-07|
    US10738261B2|2020-08-11|
    SG11201800901UA|2018-03-28|
    WO2017021426A1|2017-02-09|
    FR3039835B1|2019-07-05|
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    法律状态:
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    优先权:
    申请号 | 申请日 | 专利标题
    FR1557492|2015-08-03|
    FR1557492A|FR3039835B1|2015-08-03|2015-08-03|USE OF A FATTY AMINE FOR PREVENTING AND / OR REDUCING METALLIC LOSS OF PARTS IN AN ENGINE|FR1557492A| FR3039835B1|2015-08-03|2015-08-03|USE OF A FATTY AMINE FOR PREVENTING AND / OR REDUCING METALLIC LOSS OF PARTS IN AN ENGINE|
    US15/750,312| US10738261B2|2015-08-03|2016-08-03|Use of a fatty amine for preventing and/or reducing the metal losses of the parts in an engine|
    EP16745760.5A| EP3331975A1|2015-08-03|2016-08-03|Use of a fatty amine for preventing and/or reducing the metal losses of the parts in an engine|
    KR1020187003438A| KR20180036723A|2015-08-03|2016-08-03|Use of fatty amines to prevent and / or reduce metal loss of parts in an engine|
    JP2018506315A| JP6833813B2|2015-08-03|2016-08-03|Use of aliphatic amines to prevent and / or reduce metal loss of parts in engines|
    RU2018103966A| RU2018103966A3|2015-08-03|2016-08-03|
    CN201680045002.XA| CN107922876B|2015-08-03|2016-08-03|Use of fatty amines for preventing and/or reducing metal loss of components in engines|
    BR112018002388-4A| BR112018002388A2|2015-08-03|2016-08-03|use of an amine grease to prevent and / or reduce metal loss of parts in an engine|
    PCT/EP2016/068477| WO2017021426A1|2015-08-03|2016-08-03|Use of a fatty amine for preventing and/or reducing the metal losses of the parts in an engine|
    SG11201800901UA| SG11201800901UA|2015-08-03|2016-08-03|Use of a fatty amine for preventing and/or reducing the metal losses of the parts in an engine|
    HK18110845.6A| HK1251606A1|2015-08-03|2018-08-23|Use of a fatty amine for preventing and/or reducing the metal losses of the parts in an engine|
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